Dudley Lab Research Publications [26] Tummatorn, J.; Dudley, G. B. Ring-opening/fragmentation of dihydropyrones for the synthesis of homopropargyl alcohols. J. Am. Chem. Soc. 2008, 130, in press. [25] Kozytska, M. V.; Dudley, G. B. On the intramolecular pyrone Diels-Alder approach to basiliolide B. Tetrahedron Lett. 2008, 49, 2899-2901. [24] Engel, D. A.; Lopez, S. S.; Dudley, G. B. Lewis acid-catalyzed Meyer-Schuster reactions: methodology for the olefination of aldehydes and ketones. Tetrahedron 2008, 64, invited contribution, in press. [23] Albiniak, P. A.; Amisial, S. M.; Dudley, G. B.; Hernandez, J. P.; House, S. E.; Matthews, M. E.; Nwoye, E. O.; Reilly, M. K.; Tlais, S. F. Stable oxypyridinium triflate (OPT) salts for the synthesis of halobenzyl ethers. Synth. Commun. 2008, 38, 656-665. Dedicated to Prof Ken Goldsby for his support of undergraduate research at FSU. [22] Tummatorn, J.; Albiniak, P. A.; Dudley, G. B. Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate. J. Org. Chem. 2007, 72, 8962-8964. [21] Albiniak, P. A.; Dudley, G. B. Thermally generated phenylcarbenium ions: acid-free and self-quenching Friedel-Crafts reactions. Tetrahedron Lett. 2007, 48, 8097-8100. [20] Yang, J.; Dudley, G. B. Conjugate addition of organocopper reagents in dichloromethane to alpha,beta-unsaturated esters. Tetrahedron Lett. 2007, 48, 7887-7889. [19] Dudley, G. B.; Engel, D. A.; Lam, H.; Poon, K. W. C.; Singletary, J. A. Synthesis of dihydro-epi-deoxyarteannuin B. Org. Lett. 2007, 9, 2839-2842. [18] Poon, K. W. C.; Albiniak, P. A.; Dudley, G. B. Protection of alcohols using 2-benzyloxy-1-methylpyridinium trifluoromethanesulfonate: methyl (R)-(-)-3-benzyloxy-2-methyl propanoate. Org. Synth. 2007, 84, 295-305. [17] Lopez, S. S.; Engel, D. A.; Dudley, G. B. The Meyer-Schuster rearrangement of ethoxyalkynyl carbinols. Synlett 2007, 949-953. [16] Nwoye, E. O.; Dudley, G. B. A method for the synthesis of para-methoxybenzyl (PMB) ethers under effectively neutral conditions. Chem. Commun. 2007, 1436-1437. [15] Engel, D. A.; Dudley, G. B. Olefination of Ketones Using A Gold(III)-Catalyzed Meyer-Schuster Rearrangement. Org. Lett. 2006, 8, 4027-4029. [14] Kamijo, S.; Dudley, G. B. Cyclic Vinylogous Triflate Hemiacetals as New Surrogates for Alkynyl Aldehydes. Tetrahedron Lett. 2006, 47, 5629-5632. [13] Kamijo, S.; Dudley, G. B. Tandem Nucleophilic Addition/Fragmentation Reactions and Synthetic Versatility of Vinylogous Acyl Triflates. J. Am. Chem. Soc. 2006, 128, 6499-6507. [12] Poon, K. W. C.; Dudley, G. B. Mix-and-Heat Benzylation of Alcohols using a Bench-Stable Pyridinium Salt. J. Org. Chem. 2006, 71, 3923-3927. [11] Jones, D. M.; Kamijo, S.; Dudley, G. B. Grignard-Triggered Fragmentation of Vinylogous Acyl Triflates: Synthesis of (Z)-6-Heneicosen-11-one, the Douglas Fir Tussock Moth Sex Pheromone. Synlett 2006, 936-938. [10] House, S. E.; Poon, K. W. C.; Lam, H.; Dudley, G. B. p-Siletanylbenzylidene Acetal: Oxidizable Protecting Group for Diols. J. Org. Chem. 2006, 71, 420-422. [9] Kamijo, S.; Dudley, G. B. Claisen-Type Condensation of Vinylogous Acyl Triflates. Org. Lett. 2006, 8, 175-177. [8] Poon, K. W. C.; House, S. E.; Dudley, G. B. A Bench-Stable Organic Salt for Benzylation of Alcohols. Synlett 2005, 3142-3144. [7] Briggs, T. F.; Dudley, G. B. Synthesis of the Floresolide B Hydroquinone Lactone Core using Ring-Closing Metathesis. Tetrahedron Lett. 2005, 46, 7793-7796. [6] Salamone, S. G.; Dudley, G. B. A Ring Expansion Approach to Roseophilin. Org. Lett. 2005, 7, 4443-4445. [5] Kozytska, M. V.; Dudley, G. B. Siletanylmethyllithium: An Ambiphilic Organosilane. Chem. Commun. 2005, 3047-3049. [4] Lam, H.; House, S. E.; Dudley, G. B. The para-Siletanylbenzyl (PSB) Ether: A Peroxide-Cleavable Protecting Group for Alcohols and Phenols. Tetrahedron Lett. 2005, 46, 3283-3285. [3] Kamijo, S.; Dudley, G. B. A Tandem Carbanion Addition/Carbon-Carbon Bond Cleavage Yields Alkynyl Ketones. J. Am. Chem. Soc. 2005, 127, 5028-5029. [2] Singletary, J. A.; Lam, H.; Dudley, G. B. A Succinct Method for Preparing the Stork-Jung Vinylsilane Robinson Annulation Reagent. J. Org. Chem. 2005, 70, 739-741. [1] Sunderhaus, J. D.; Lam, H.; Dudley, G. B. Oxidation of Carbon-Silicon Bonds: The Dramatic Advantage of Strained Siletanes. Org. Lett. 2003, 5, 4571-4573. Book Chapters and Reviews [IV] Kozytska, M. V.; Dudley, G. B. Four-membered rings with one silicon, germanium, tin, or lead atom. In Comprehensive Heterocyclic Chemistry III. Katritsky, A. R., Ed., Pergamon Press: New York. (invited chapter in press). [III] Dudley, G. B. 2-Benzyloxy-1-methylpyridinium trifluoromethanesulfonate. In Electronic Encylopedia of Reagents for Organic Synthesis Paquette, L., Fuchs, P., Crich, D., Molander, G., Eds., John Wiley & Sons: Chichester. (invited contribution, in press). [II] Danheiser, R. L.; Dudley, G. B.; Austin, W. F. Product class 13: alkenylketenes. In Science of Synthesis: Houben-Weyl Methods of Molecular Transformation. Bellus, D., Danheiser, R. L., Eds., Thieme: Stuttgart, 2006; Vol. 23, Chapter 13, pp 492-568. [1] Austin, W. F.; Kowalczyk, J. J.; Dudley, G. B.; Danheiser, R. L. Product class 7: alkylideneketenes. In Science of Synthesis: Houben-Weyl Methods of Molecular Transformation. Bellus, D., Danheiser, R. L., Eds., Thieme: Stuttgart, 2006; Vol. 23, Chapter 7, pp 245-258. Patents [ii] Dudley, G. B. Reagent for synthesis of para-methoxybenzyl (PMB) ethers and associated methods. US Patent Application No. 11/865,952 (2007). [i] Dudley, G. B. Compounds and methods of arylmethylation (benzylation) as protection for alcohol groups. US Patent Application No. 11/399,300 (2006).