|
Reactions of Arenes
(Carey, Chap. 11 & 12) |
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| Reaction | Product | Notes | |||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 
|
| prep. of nitrobenzenes 
| prep. of benzenesulfonic acids 
| Friedel-Crafts reaction. carbocation intermediate; rearrangement possible; NOT with meta-directors 
| Friedel-Crafts reaction. acyl cation intermediate; no rearrangement; NOT with meta-directors 
| Chap. 24.6 prep. of phenols 
| Chap. 22.10 prep. of anilines; SnCl2 selective for NO2 
| Zn selective for aryl C=O 
| Must have at least 1 benzylic H; prep. of benzoic acids; structure elucidation 
| benzylic H only free-radical reaction 
| benzylic Y only 
| Birch reduction | ||||||||||||||||||||||