Hour Test I (canary) Name__________________________ CHM 1045 (Dr. Light) Soc.Sec.Num._____________________ February 9, 1996 8:00 am Recitation Section_______ This exam consists of 4 pages. Make sure you have one of each. Print your name at the top of each page now. A blank scratch sheet and a periodic chart are provided. Please do not write on the periodic chart, and turn it in with your test. You may discard the scratch sheet. Show your work on calculations, including unit conversions, and give answers in the correct units and appropriate number of significant figures. In problems involving molecular and formula weights, you may use values rounded to the nearest 0.1 amu. If anything confuses you or is not clear, raise your hand and ask! (6) 1. Mercury has a density of 13.6 g/cm3. A laboratory beaker weighs 13.5 g empty and 39.8 g when filled with water. What would be the weight of the beaker if filled with mercury (i.e. the total weight of beaker plus mercury). (Remember, the density of water is 1.00 g/cm3. (4) 3. Name the following compounds: Ba(ClO3)2 ____________________ Li2SO3 ____________________ (4) 4. Write the formulas for the following: lead (II) phosphate ____________________ diphosphorus pentoxide ____________________ (8) 5. Give the atomic symbol, including Z, A, and q for atoms or ions containing the following numbers of particle: (a) 16 p, 16 n, 18 e (b) 30 p, 35 n, 30 e (6) 6. Give the number of protons, neutrons, and electrons in the following: Nuclide protons neutrons electrons 73Ge _______ ________ ________ 108Ag+1 ________ ________ ________ (3) 7. Which of the following men (circle your answer) discovered radioactivity while studying whether x-rays could be produced by flourescence of minerals. Becquerel, Rutherford, Thompson, Millikan, Dalton, Priestly (7) 8. Balance the following chemical equations: (a) ____Al2O3 + ____H2O -----> ____Al(OH)3 (b) ____Sr + ____HCl -----> ____SrCl2 + ____H2 (15) 9. Complete and balance the chemical equations for: (a) Reaction of sodium with water. (b) Complete combustion of lauric acid (C12H24O2). (c) Reaction of hydrofluoric acid with magnesium hydroxide. (6) 10. Calculate the number of moles in 93.8 grams of P2O5. (8) 11. Calculate the number of molecules in 21.4 g of methyl alcohol, CH4O. (10) 12. A compound containing only carbon, hydrogen and oxygen was shown by combustion analysis to consist of 62.1% C and 10.3% H. What is its empirical formula? 13. Given the following chemical equation: 2 HBr + Ca(OH)2 -----> CaBr2 + 2 H2O (8) (a) 4.25 g of HBr are dissolved in water and the solution is titrated with a solution of Ca(OH)2. The titration requires 55.3 mL of the Ca(OH)2 solution. What is the molarity of the Ca(OH)2 solution? (6) (b) 32 mL of a solution of 0.25 M Ca(OH)2 is mixed with 42 mL of a solution of 0.25 M HBr. Which is the limiting reagent? (Show your work). (6) (c) In part (b) above, how many grams of CaBr2 will be formed? (3) (d) In part (b) above, how many moles (or millimoles) of the excess reagent will be left?