How Acid Rain is Destroying History

Experiment 12 How Acid Rain is Destroying History


 


Introduction/Background

     Acid rain is more acidic than normal rain and forms through a complex process of chemical reactions involving air pollution. The two most important pollutants that contribute to the formation of acid rain are oxides of nitrogen and sulfur dioxide, which react with moisture in the atmosphere to form nitric and sulfuric acid.

acid rain formation

     The sulfur and nitrogen compounds that contribute to acid rain primarily come from man-made sources, such as industries and utilities. Emissions also come from automobiles and other forms of transportation and industrial processes, such as smelting. Acid rain can harm forests and crops, damage bodies of water, and contribute to the damage of statues and buildings. Researchers are considering the possible effects of acid rain on human heath. These acidic pollutants can be deposited through rain, snow, fog, dew, or sleet. Large quantities can also be deposited in a dry form through dust. Pollutants that contribute to acid rain may be carried hundreds of miles before being deposited on the earth. Because of this, it is sometimes difficult to determine the specific sources of these acid rain pollutants.
Key Concepts

     Previously, in this course, we have observed the reactions that occur when an acid comes in contact with a base. Specifically, the reaction between acetic acid (vinegar) and sodium bicarbonate (Tums, Alka Seltzer). You will remember that the sodium bicarbonate dissolves. The same thing happens when acid rain (sulfuric or nitric acid) comes in contact with calcium carbonate which is the main component of limestone and cement.
     acid rain on statue
Acid rain melts a statue
acid rain on building
Acid rain melts a building


Example 1: Balancing an acid/base reaction:

One possible acid rain reaction is HNO3 + CaCO3.

This is a metathesis reaction which means the ions involved "swap partners".
Answer: 1st separate the compounds into their component ions:

      H+ + NO3- + Ca2+ + CO32- → ?
Now swap partners pairing up negative ions with positive ions and balancing the charges:

     HNO3 + CaCO3H2CO3 + Ca(NO3)2


Example 2: Balancing an acid/base reaction:

A second possible acid rain reaction is H2SO4 + CaCO3.

This is also metathesis reaction which means the ions involved "swap partners". Using example 1 as a guide you try:

Answer: 1st separate the compounds into their component ions:

      click to reveal

Now swap partners pairing up negative ions with positive ions and balancing the charges:

     click to reveal



Glossary

Related Materials

Acid Rain Report (http://www.angelfire.com/ks3/acidrainreport/acid.html)
EPA Acid Rain Site (http://www.epa.gov/airmarkets/arp)
USGS Acid Rain Data and Reports (http://btdqs.usgs.gov/acidrain )
The Green Lane: Acid Rain (http://www.ec.gc.ca/acidrain )